Conjugated Microporous Networks on the Basis of 2,3,5,6-Tetraarylated Diketopyrrolo[3,4-c]pyrrolea

نویسندگان

  • Kai Zhang
  • Bernd Tieke
  • Filipe Vilela
  • Peter J Skabara
چکیده

π-Conjugated microporous networks have been prepared from the tetraarylated diketopyrrolo[3,4-c]pyrrole unit as a tetrafunctional building block. The reactions are carried out using microwave-assisted Yamamoto or Sonogashira cross-coupling. Red insoluble powders are obtained, showing intense fluorescence. The polymer networks exhibit a high gas storage capability, with BET surface areas up to about 500  m(2)·g(-1).

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عنوان ژورنال:

دوره 32  شماره 

صفحات  -

تاریخ انتشار 2011